Martin Jarenmark
Research engineer
Insertion of carbon dioxide into (PCP)Pd-II-Me bonds
Author
Summary, in English
A (PCP)PdMe complex has been synthesized and structurally characterized, displaying a very long Pd-Me bond. It is reactive toward CO2 insertion, giving the corresponding acetate in quantitative yield. The methyl complex can be regenerated using ZnMe2, and catalytic carboxylation is possible in benzene.
Department/s
- Centre for Analysis and Synthesis
- Department of Chemistry
Publishing year
2005
Language
English
Pages
4500-4502
Publication/Series
Organometallics
Volume
24
Issue
19
Document type
Journal article
Publisher
The American Chemical Society (ACS)
Topic
- Organic Chemistry
Status
Published
ISBN/ISSN/Other
- ISSN: 1520-6041